Question: Identify the base on the left and

> Sir William Ramsey (Lord Rayleigh) prepared nitrogen samples by several different methods. The density of each sample was measured as the mass of gas required to fill a particular flask at a certain temperature and pressure. Masses of nitrogen samples pr

> Calculate the molar solubility of ZnCO3 in a solution buffered to a pH of 7.50.

> Calculate the molar solubility of ZnCO3 in a solution buffered to a pH of 7.00.

> Calculate the molar solubility of MnS (pink) in a solution with a constant 3H3O14 of a. 3.00 × 10-5 M b. 2.50 × 10-7 M

> A 0.4723-g sample of primary-standard-grade Na2CO3 required 34.78 mL of an H2SO4 solution to reach the end point in the reaction CO3 22 + 2H1 → H2O + CO21g2 What is the molar concentration of the H2SO4?

> Calculate the concentration of CuS in a solution in which 3H3O14 is held constant at a. 2.0 × 10-1 M b. 2.0 × 10-4 M.

> Calculate the molar solubility of PbS in a solution in which 3H3O14 is held constant at a. 3.0 × 10-1 M b. 3.0 × 10-4 M.

> Calculate the molar solubility of BaSO4 in a solution in which 3H3O14 is a. 3.5 M. b. 0.75 M. c. 0.080 M. d. 0.100 M.

> Calculate the molar solubility of ZnC2O4 in a solution that has a fixed H3O1 concentration of a. 1.0 × 10-6 M. b. 1.0 × 10-7 M. c. 1.0 × 10-9 M. d. 1.0 × 10-11 M.

> Write the charge-balance equations for the solutions in Problem 9-5.

> Write the mass-balance expressions for a solution that is a. 0.2 M in HF. b. 0.25 M in NH3. c. 0.10 M in H3PO4. d. 0.15 M in Na2HPO4. e. 0.0500 M in HClO2 and 0.100 M in NaClO2. f. 0.12 M in NaF and saturated with CaF2. g. 0.100 M in NaOH and satu

> Neglecting any effects caused by volume changes, would you expect the ionic strength to (1) increase, (2) decrease, or (3) remain essentially unchanged when NaOH is added to a dilute solution of a. magnesium chloride [Mg1OH221s2] forms? b. hydrochlor

> Two different analytical methods were used to determine residual chlorine in sewage effluents. Both methods were used on the same samples, but each sample came from various locations with differing amounts of contact time with the effluent. Two methods w

> Find the amount of the indicated element (in moles) in a. 5.32 g of B2O3. b. 195.7 mg of Na2B4O7 ? 10H2O. c. 4.96 g of Mn3O4. d. 333 mg of CaC2O4.

> List several general properties of activity coefficients.

> Describe the preparation of a. 1.00 L of 0.150 M KMnO4 from the solid reagent. b. 2.50 L of 0.500 M HClO4, starting with a 9.00 M solution of the reagent. c. 400 mL of a solution that is 0.0500 M in I2, starting with MgI2. d. 200 mL of 1.00% (w>v) aq

> Make a distinction between a. activity and activity coefficient. b. thermodynamic and concentration equilibrium constants.

> Design and construct a spreadsheet to calculate activity coefficients in a format similar to Table 8-2. Enter values of aX in cells A3, A4, A5, and so forth, and enter ionic charges in cells B3, B4, B5, and so forth. Enter in cells C2:G2 the same set of

> Calculate the % relative error in hydronium ion concentration by using concentrations instead of activities in calculating the pH of the following buffer solutions using the thermodynamic constants found in Appendix 3. a. 0.175 M HOAc and 0.275 M NaOAc

> Calculate the % relative error in solubility by using concentrations instead of activities for the following compounds in 0.0350 M KNO3 using the thermodynamic solubility products listed in Appendix 2. a. CuCl 1aCu1 5 0.3 nm2 b. Fe1OH22 c. Fe1OH23 d. La

> Calculate the solubilities of the following compounds in a 0.0167 M solution of Ba1NO322 using (1) activities and (2) molar concentrations: a. AgIO3. b. Mg1OH22. c. BaSO4. d. La1IO323.

> Calculate the solubilities of the following compounds in a 0.0275 M solution of Mg1ClO422 using (1) activities and (2) molar concentrations: a. AgSCN. b. PbI2. c. BaSO4. d. Cd2Fe1CN26.

> Use activities to calculate the molar solubility of Zn1OH22 in a. 0.0150 M KCl. b. 0.0250 M K2SO4. c. the solution that results when you mix 40.0 mL of 0.250 M KOH with 60.0 mL of 0.0250 M ZnCl2. d. the solution that results when you mix 20.0 mL of 0.1

> For a solution in which m 5 6.5 3 1022, calculate K9sp for a. AgSCN. b. PbI2. c. La1IO323. d. MgNH4PO4.

> The homogeneity of the chloride level in a water sample from a lake was tested by analyzing portions drawn from the top and from near the bottom of the lake, with the following results in ppm Cl: a. Apply the t test at the 95% confidence level to determ

> Calculate activity coefficients for the species in Problem 8-10 by linear interpolation of the data in Table 8-2.

> Describe the preparation of a. 500 mL of 0.0750 M AgNO3 from the solid reagent. b. 2.00 L of 0.325 M HCl, starting with a 6.00 M solution of the reagent. c. 750 mL of a solution that is 0.0900 M in K1, starting with solid K4Fe1CN26. d. 600 mL of 2.00

> Express the solubility-product constant for each substance in Problem 7-8 in terms of its molar solubility S.

> Use Equation 8-5 to calculate the activity coefficient of

> Calculate the ionic strength of a solution that is a. 0.025 M in FeSO4. b. 0.25 M in 1NH422CrO4. c. 0.25 M in FeCl3 and 0.15 M in FeCl2. d. 0.025 M in La1NO323 and 0.050 M in Fe1NO322.

> What is the numerical value of the activity coefficient of aqueous ammonia 1NH32 at an ionic strength of 0.2?

> Explain why the initial slope for Ca21 in Figure 8-3 is steeper than that for K1?

> Explain why the activity coefficient for a neutral molecule is usually 1

> Explain why the activity coefficient for dissolved ions in water is usually less than that for water itself.

> Neglecting any effects caused by volume changes, would you expect the ionic strength to (1) increase, (2) decrease, or (3) remain essentially unchanged by the addition of iron(III) chloride to a. HCl? b. NaOH? c. AgNO3?

> What is the standard error of a mean? Why is the standard deviation of the mean lower than the standard deviation of the data points in a set?

> Distinguish between a. The sample variance and the population variance. b. The meaning of the word sample as it is used in a chemical and in a statistical sense.

> Write the equilibrium-constant expressions and obtain numerical values for each constant in a. The basic dissociation of aniline, C6H5NH2. b. The acidic dissociation of hypochlorous acid, HClO. c. The acidic dissociation of methyl ammonium hydrochloride

> Differentiate between a. Parameter and statistic. b. Population mean and sample mean. c. Random and systematic error. d. Accuracy and precision.

> Go to http://dx.doi.org/10.18434/T43G6C, where you will find a link to the NIST Statistical Reference Datasets site. Find the Dataset Archives, locate the Univariate Summary Statistics section, and select the Mavro data set. This actual data set is the r

> Calculate a pooled estimate of s from the following spectrophotometric analysis for NTA (nitrilotriacetic acid) in water from the Ohio River:

> Nine samples of illicit heroin preparations were analyzed in duplicate by a gas chromatographic method. The samples can be assumed to have been drawn randomly from the same population. Pool the following data to establish an estimate of s for the procedu

> Describe the steps in a sampling operation.

> State quantitatively the null hypothesis H0 and the alternative hypothesis Ha for the following situations, and describe the type I and type II errors. If these hypotheses were to be tested statistically, comment on whether a one- or two-tailed test woul

> In a volumetric determination of an analyte A, the data obtained and their standard deviations are as follows: From the data, find the coefficient of variation of the final result for the %A that is obtained by using the equation that follows and assumin

> Six bottles of wine of the same variety were analyzed for residual sugar content with the following results: / Evaluate the standard deviation s for each set of data. Pool the data to obtain an absolute standard deviation for t

> Analysis of several plant-food preparations for potassium ion yielded the following data: The preparations were randomly drawn from the same population. Find the mean and standard deviation Ñ• for each sample. Obtain the pooled

> Chapter 22 shows that quantitative molecular absorption spectrometry is based on Beer’s law, which can be written as -log T = εbcX where T is the transmittance of a solution of an analyte X, b is the thickness of the absorbing solution, cX is the molar c

> Calculate the molar concentration of a 20.0% solution (w/w) of KCl that has

> Chapter 26 describes inductively coupled plasma atomic emission spectrometry. In that method, the number of atoms excited to a particular energy level is a strong function of temperature. For an element of excitation energy E in joules (J), the measured

> The standard deviation in measuring the diameter d of a sphere is ±0.02 cm. What is the standard deviation in the calculated volume V of the sphere if d = 2.35 cm?

> Define a. Sample standard deviation. b. Coefficient of variation. c. Variance. d. Standard error of the mean.

> Calculate the absolute standard deviation and the coefficient of variation for the results of the following calculations. Round each result to include only significant figures. The numbers in parentheses are absolute standard deviations. a. y = log[2.00(

> The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the percent relative error if the total volume of titrant is

> What is the object of the sampling step in an analysis?

> Estimate the absolute deviation and the coefficient of variation for the results of the following calculations. Round each result so that it contains only significant digits. The numbers in parentheses are absolute standard deviations. a. y = 3.95(±0.03)

> Name three types of systematic errors.

> Suggest two sources of systematic error and two sources of random error in measuring the length of a 3-m table with a 1-m metal rule.

> Calculate the molar concentration of a solution that is 50.0% NaOH (w/w) and has a specific gravity of 1.52.

> Explain the difference between a. random and systematic error. b. constant and proportional error. c. absolute and relative error. d. mean and median.

> Find the mean and median of each of the following sets of data. Determine the deviation from the mean for each data point within the sets, and find the mean deviation for each set. Use a spreadsheet if it is convenient. 6

> Simplify the following quantities using a unit with an appropriate prefix: a. 5.8 × 108 Hz. b. 4.37 × 1027 g. c. 9.31 × 107 mmol. d. 8.3 ×1010 s. e. 3.96 × 106 nm. f. 53,000 g.

> A loss of 0.4 mg of Zn occurs in the course of an analysis for that element. Calculate the percent relative error due to this loss if the mass of Zn in the sample is a 30 mg. b 100 mg. c 300 mg. d 500 mg.

> The color change of a chemical indicator requires an overtitration of 0.03 mL. Calculate the percent relative error if the total volume of titrant is a 50.00 mL. b 10.0 mL. c 25.0 mL. d 30.0 mL

> The method described in Problem 3-8 is to be used for the analysis of ores that assay about 1.2% gold. What minimum sample mass should be taken if the relative error resulting from a 0.4-mg loss is not to exceed a 20.1%? b 20.4%? c 20.8%? d 21.1%?

> A method of analysis yields masses of gold that are low by 0.4 mg. Calculate the percent relative error caused by this result if the mass of gold in the sample is a. 500 mg. b. 250 mg. c. 125 mg. d. 60 mg.

> A 0.005-g sample of a rock is to be analyzed, and iron is to be determined at the ppm level. Determine the type of analysis and type of constituent.

> What kind of systematic errors are detected by varying the sample size?

> Describe how systematic method errors may be detected.

> What mass of solute in grams is contained in a. 450.0 mL of 0.0986 M H2O2? b. 26.4 mL of 9.36 3 1024 M benzoic acid (122.1 g/mol)? c. 2.50 L of a solution that contains 23.4 ppm SnCl2? d. 21.7 mL of 0.0214 M KBrO3?

> Describe at least three ways in which a systematic error might occur while using a pipet to transfer a known volume of liquid.

> Describe at least three systematic errors that might occur while weighing a solid on an analytical balance.

> Exactly 750.0 mL of a solution that contains 500.0 ppm of Ba(NO3)2 is mixed with 200.0 mL of a solution that was 0.04100 M in Al2(SO4)3. a. What mass of solid BaSO4 is formed? b. What is the molar concentration of the unreacted reagent [Al2(SO4)3 or Ba(N

> What volume of 0.01000 M AgNO3 is required to precipitate all of the I- in 150 mL of a solution that contains 22.50 ppt KI?

> Identify the acid on the left and its conjugate base on the right in the following equations:

> What mass of MgNH4PO4 precipitates when 200.0 mL of a 1.000% (w/v) solution of MgCl2 is treated with 40.0 mL of 0.1753 M Na3PO4 and an excess of NH4+? What is the molar concentration of the excess reagent (Na3PO4 or MgCl2) after the precipitation is comp

> Exactly 75.00 mL of a 0.3132 M solution of Na2SO3 is treated with 150.0 mL of 0.4025 M HClO4 and boiled to remove the SO2 formed. a. What is the mass in grams of SO2 that is evolved? b. What is the concentration of the unreacted reagent (Na2SO3 or HClO4)

> Exactly 25.0 mL of a 0.3757 M solution of Na3PO4 is mixed with 100.00 mL of 0.5151 M HgNO3. a. What mass of solid Hg3PO4 is formed? b. What is the molar concentration of the unreacted species (Na3PO4 or HgNO3) after the reaction is complete?

> Find the number of K+ ions in 1.43 mole of K2HPO4?

> Exactly 0.118 g of pure Na2CO3 is dissolved in 100.0 mL of 0.0731 M HCl. a. What mass in grams of CO2 is evolved? b. What is the molar concentration of the excess reactant (HCl or Na2CO3)?

> Find the number of millimoles of solute in a. 386 mL of 0.210 M HClO4. b. 25.0 L of 8.05 × 10-3 M K2CrO4. c. 4.50 L of an aqueous solution that contains 6.95 ppm of AgNO3. d. 537 mL of 0.0200 M KOH.

> What mass of solid PbCl2 (278.10 g/mol) is formed when 200 mL of 0.125 M Pb2+ is mixed with 400 mL of 0.175 M Cl?

> What mass of solid La(IO3)3 (663.6 g/mol) is formed when 50.0 mL of 0.250 M La3+ is mixed with 75.0 mL of 0.302 M IO3-?

> Describe the preparation of a. 2.50 L of 0.0250 M KMnO4 from the solid reagent. b. 4.00 L of 0.250 M HClO4, starting with an 8.00 M solution of the reagent. c. 500 mL of a solution that is 0.0200 M in I-, starting with MgI2. d. 200 mL of 1.00% (w/v) aque

> Describe the preparation of a. 500 mL of 0.1000 M AgNO3 from the solid reagent. b. 1.00 L of 0.1000 M HCl, starting with a 6.00 M solution of the reagent. c. 250 mL of a solution that is 0.0810 M in K+, starting with solid K4Fe(CN)6. d. 500 mL of 3.00% (

> Is the following statement true or false or both? Define your answer with equations, examples, or graphs. “A buffer maintains the pH of a solution constant.”

> Describe the preparation of 750 mL of 3.00 M HNO3 from the commercial reagent that is 70.5% HNO3 (w/w) and has a specific gravity of 1.42.

> Give two examples of units derived from the fundamental base SI units.

> What volume of 2.00 M NaOH must be added to 200.0 mL of 1.00 M glycolic acid to produce a buffer solution having a pH of 4.15?

> Describe the preparation of 500 mL of 3.00 M H3PO4from the commercial reagent that is 86% H3PO4(w/w) and has a specific gravity of 1.71.

> The following table gives the sample means and standard deviations for six measurements each day of the purity of a polymer in a process. The purity is monitored for 24 days. Determine the overall mean and standard deviation of the measurements, and cons

> What mass of solute in milligrams is contained in a. 26.0 mL of 0.250 M sucrose (342 g/mol)? b. 2.92 L of 5.23 3 1024 M H2O2? c. 673 mL of a solution that contains 5.76 ppm Pb1NO322 1331.20 g>mol2? d. 6.75 mL of 0.0426 M KNO3?

> What mass of KIO3 is needed to convert the copper in 0.1570 g of CuSO4 . 5H2O to Cu1IO322?

> What volume of 0.200 M HCl must be added to 500.0 mL of 0.300 M sodium mandelate to produce a buffer solution with a pH of 3.25?

> Describe the preparation of a. 1.50 L of 21.0% (w/v) aqueous glycerol (C3H8O3, 92.1 g/mol). b. 1.50 kg of 21.0% (w/w) aqueous glycerol. c. 1.50 L of 21.0% (v/v) aqueous glycerol.

> What mass of sodium glycolate should be added to 400.0 mL of 1.00 M glycolic acid to produce a buffer solution with a pH of 4.25?

> Describe the preparation of a. 500 mL of 5.25% (w/v) aqueous ethanol (C2H5OH, 46.1 g/mol). b. 500 g of 5.25% (w/w) aqueous ethanol. c. 500 mL of 5.25% (v/v) aqueous ethanol.

> What mass of sodium formate must be added to 500.0 mL of 1.00 M formic acid to produce a buffer solution that has a pH of 3.75?

> Why are Ce4+ solutions never used for the titration of reductants in basic solutions?

> Why are Ce4+ solutions never used for the titration of reductants in basic solutions?